국립부경대학교 화학과

(광)전기화학, 분자소자, 분광분석 

"태초에 빛이 있으라"는 어느 종교의 표현을 빌릴 필요도 없이 우주의 시작은 "BIG BANG"후의 빛 (광자, photo)의 전차에서 시작되었다고 현대과학은 추측하고 있다.
현 지구 상에 존재하는 생명체의 근원적인 에너지는 태양으로 부터 오는 광에너지이다.
자연계에는 이러한 광에너지를 매우 복잡한 생물학적인 계를 통해 변환하여 생명현상에 활용하여 생태계를 유지하고 있다.
인류는 자연 생태계가 수억년전에 이룩한 광에너지의 변환 형태인 화석연료를 주로 활용하여 현재의 과학 문명을 이루었다.

이러한 측면에서 볼 때 광에너지에 대한 연구는 가장 근원적인 연구과제라고 볼 수 있으며 인류문명의 존폐가 에너지의 활용을 어떻게 효율적으로 조절하느냐에 달려있다고 볼 때 가장 근원적인 에너지인 광에너지 변환에 관한 연구는 또한 인류적 과제이기도 하다.
 

본 연구실에서는 이러한 광에너지를 보다 효율적으로 변환하고 활용할 수 있는 계에 대한 연구들, 대체에너지를 위한 인공공학성계의 개발, 광전지 및 광전기화학전지의 개발, 광변환소재 (광 스위치/광전도성막) 광 기억소자의 개발, 폐기물 처리를 위한 광촉매의 개발등과 현대과학의 가장 핵심기술이 될 "Nano Technology"와 관련된 분자수준에서 제어가능한 기능성 소자의 연구개발, 반도체 및 자기성 나노입자의 합성 및 물성연구, 자기조립법을 활용한 기능성 유기박막 및 유기/나노입자 혼성박막의 제조 및 특성 연구 등도 함께 수행하고 있다. 

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1. Y. I. Kim and K. J. Shin, "Study of Vibrational Dephasing of Simple Molecules in Liquids" Bull. Korean Chem. Soc. 1987, 8, 105-110

2. D. Rong, H.-G. Hong, Y. I. Kim, J. S. Krueger, J. E. Mayer, and T. E. Mallouk, "Electrochemistry and Photochemistry of Transition Metal Complexes in Well-Ordered Surface Layers" Coor. Chem. Rev. 1990, 97, 237-248 

3. D. Rong, Y. I. Kim, and T. E. Mallouk, "Electrochemistry and Photochemistry of Pillared-Clay-Modified Electrodes" Inorg. Chem. 1990, 29, 1531-1535
 
4. Y. I. Kim, R. L. Riley, M. J. Huq, S. Salim, A. N. Le, and T. E. Mallouk, "Zeolitic Materials as Organizing Media for Semiconductor-Based Artificial Photosynthetic Systems", R. L. Bedard, T. Bein, M. E. Davis, J. Garces, V. A. Maroni, and G. D. Stucky Eds. MRS Sym. Proceedings (Synthesis/Characterization and Novel Applications of Molecular Sieve Materials), 1991, 233, 145-156

5. Y. I. Kim, S. Salim, M. J. Huq, and T. E. Mallouk, "Visible Light Photolysis of Hydrogen Iodide Using Sensitized Layered Semiconductor Particles" J. Am. Chem. Soc., 1991, 113, 9561-9563

6. Y. I. Kim, R. L. Riley, E. H. Yonemoto, D. Rong, and T. E. Mallouk, "Self-Assembling Electron Transport Chains in Zeolites: Molecular Bilayer Rectifiers and Photodiodes" T. Bein Ed. ACS Sym. Series  (Superamolecular Architecture: Synthetic Control in Thin Films and Solids), 1992, 499, 333-346

7. Y. I. Kim and T. E. Mallouk, "Dynamic Electron Transfer Quenching of the Tris(2,2'-bipyridyl)ruthenium(II) MLCT Excited State by Intrazeolitic Methylviologen Ions" J. Phys. Chem. 1992, 96, 2879-2885

8. E. H. Yonemoto, R. L. Riley, Y. I. Kim, S. J. Atherton, R. H. Schmehl, and T. E. Mallouk, "Photoinduced Electron Transfer in Covalently Linked Ruthenium Tris(bipyridyl) - Viologen Molecules: Observation of Back Electron Transfer in the Marcus Inverted Region" J. Am. Chem. Soc. 1992, 114, 8081-8087

9. C. Lai, Y. I. Kim, C. M. Wang, and T. E. Mallouk, "Evidence for Carbocation Intermediates in the TiO2-Catalyzed Photochemical Fluorination of Carboxylic Acids" J. Org. Chem. 1993, 58, 1393-1399

10. E. S. Brigham, P. Snowden, Y. I. Kim, and T. E. Mallouk, "Electron and Energy Transfer as Probes of Interparticles Ion-Exchange Reactions in Zeolite Y" J. Phys. Chem. 1993, 97, 8650-8655

11. Y. I. Kim, S. J. Atherton, E. S. Brigham, and T. E. Mallouk, "Sensitized Layered Metal Oxide Semiconductor Particles for Photochemical Hydrogen Evolution from Non-sacrificial Electron Donors"  J. Phys. Chem. 1993, 97, 11802-11810

12. B. A. Gregg and Y. I. Kim, "Redox Polymer Contacts to Molecular Semiconductor Films: Toward Kinetic Control of Interfacial Exciton Dissociation and Electron-Transfer Processes"  J. Phys. Chem. 1994, 98, 2412-2417

13. E. Yonemoto, Y. I. Kim, R. H. Schmehl, J. O. Wallin, B. A. Shoulders, B. R. Richardson, J. F. Haw, and T. E. Mallouk, "Photoinduced Electron Transfer Reactions in Zeolite-Based Donor-Acceptor and Donor-Donor-Acceptor Diads and Triads" J. Am. Chem. Soc. 1994, 116, 10557-10563

14. Y. I. Kim and B. A. Gregg, "Novel Photovoltaic Effects of Highly Ordered Molecular Semiconductor Films" J. Electrochem. Re. Assoc. 1994, 2, 91-106

15. T. E. Mallouk, S. W. Keller, C. M. Bell, H.-G. Hong, H.-N. Kim, Y. I. Kim, D. M. Kaschak, D. L. Feldheim, P. J. Ollivier, S. A. Johnson, "Self-Assembly of Nanostructures from Inorganic Building Blocks" Proc. Robert A. Welch Conf. on Chemical Research, XXXIX, 1996, 123-137

16. H. K. Shim, Y. I. Kim, Y. H. Oh, "Synthesis of meso-Tetraphenyl-21-23- dioxaporphyrin" Bull. Pukyong Nat'l University, 1996, 1, 13-22

17. Y. I. Kim, S. W. Keller, J. S. Krueger, G. B. Saupe, E. H. Yonemoto, and T. E. Mallouk, "Photochemical Charge Transfer and Hydrogen Evolution Mediated by Oxide Semiconductor Assemblies" J. Phys. Chem. 1997, 101, 2491-2500

18. J. H. Bae, D. Kim, Y. I. Kim and K.-J. Kim, "Photoinduced Electron Trnasfer from Excited Ruthenium Complexes at Nanocrystalline TiO2 Electrodes" Bull. Korean Chem. Soc. 1997, 18, 567-572

19. D. K. Lee, Y. I. Kim, Y. S. Kwon, Y. S. Kang, and L. Kevan, "Electron Magnetic Resonance Study of the Photoreduction of Alkylviologens in Anionic Sodium Dodecyl Sulfate and Cataionic Dodecyltrimethylammonium Bromide Micelles" J. Phys. Chem. 1997, 101, 5319-5323

20. M. S. Lee, H. K. Shim, and Y. I. Kim, "Metal Phosphonate Multilayer Films of Perylenebis(dicarboximide) Derivatives" Proc. of 8th Molecular Electronics and Devices Symp. 1997, 8, 221-230

21. H. J. Chae, M. S. Lee, Y. I. Kim, and H. Lee, "Formation of Self-Assembled Zirconium N, N-Bis(benzyl phosphonic acid)-3,4,9,10-Perylene(dicarboximide) Multilayer Films on Silicon Substrate" Bull. Korean Chem. Soc. 1998, 19, 27-29

22. M. S. Lee, H. K. Shim, and Y. I. Kim, "Zirconium Phosphonate Multilayers of Organic Redox Couples on Nanocrystalline TiO2 Semiconductor Electrode" Mol. Cryst. and Liq. Cryst.1998, 316, 401-406

23. H. J. Che, Y. I. Kim, E.-R. Kim, and H. Lee, "Self-Assembly of Zirconium N,N-bis(benzyl phosphonic acid)-3,4,9,10-Perylenebis(dicarboximide) Multilayer Films on Silicon and Quarz Substrates" Mol. Cryst. and Liq. Cryst. 1998, 316,

24. H. Kang, C. S. Lee, D. Kim, Y. S. Kang, and Y. I. Kim, "Transformation of Nanoparticle Magnetite Prepared in Homogeneous Aqueous Solution" Bull. Korean Chem. Soc. 1998, 19, 408-411

25. D. Kim, C. S. Lee, and Y. I. Kim, "Microstructure, Electrical Properties and Nonstoichimetry of Light Enhanced Plating(LEP) Ferrite Film" Bull. Korean Chem. Soc. 1998, 19, 533-539

26. J. C. Kim, J. C. Fettinger, and Y. I. Kim, "Syntheses and Structures of Nickel(II)and Copper(II) Complexes with 14-Membered Tetraaza Macrocyclic Ligand" Inorg. Chim. Acta, 1999, 286, 67-73

27. D. Kim, K. Hwang, C. S. Lee, J. C. Sur, H. K. Shim, and Y. I. Kim, “Influence of Lewis Base on the Nonstoichimetry and the Properties of Magnetite Films Prepared by Aqueous Solution Method” Bull. Korean Chem. Soc. 1999, 20, 1313-1318

28. K. J. Cho, H. K. Shim, and Y. I. Kim, "Metal Bisphosphonate Multilayers of Perylene and Naphthalene Bi(dicarboximide) Derivatives on ITO Substrate" Syn. Metals,  2001, 117, 153-155

29. Y. I. Kim, H. Kang, D. Kim, and C. S. Lee, "Nanoparticle Ferrite Multilayers Preapred by New Self-Assembling Sequential Adsorption Method"  Bull. Korean Chem. Soc. 2003, 24, 593-599

30. T. Y. Kim, M. S. Lee, Y. I. Kim, C. S. Lee, J. C. Park, and D. Kim, "The enhanced anisotropic properties of the Fe3-xMxO4(M=Fe, Co, Mn) films deposited on glass surface from aqueous solutions on glass surface from aqueous solutions at low temperature" J. Phys. D: Appl. Phys. 2003, 36, 1451-1457

31. M. S. Lee, I. C. Cheon, and Y. I. Kim, "Photoelectrochemical Studies of Nanocrystalline TiO2 Film Electrodes" Bull. Korean Chem. Soc. 2003, 24, 1155-1162
　
32. Y. I. Kim, D. Kim, and C. S. Lee, "Synthesis and Characterization of CoFe2O4 Magnetic Nanoparticles Prepared by Temperature-Controlled Coprecipitation Method" Physica B, 2003, 337, 42-51

33. M. S. Lee, T. Y. Kim, C. S. Lee, J. C. Park, Y. I. Kim, and D. Kim, "Magnetic and Structural Anisotropy of the Co-Fe3O4 Films Deposited by the Thin-Liquid Flim Method" J. Magn. Magn. Mater. 2003, in press

34. I. C. Cheon, M. S. Lee, H. K. Shim, and Y. I. Kim, "Effect of Phosphonate-Functionalized Surface Modification on Nanocrystalline TiO2 Film Electrode" Bull. Korean Chem. Soc. 2003, 24, 1535-1537 

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